Cover Feature: Helicity Control of Supramolecular Gel Fibers Consisting of an Achiral NiII Complex in a Chiral Nematic Solvent (Chem. Eur. J. 48/2018)
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چکیده
منابع مشابه
Unexpected helicity control and helix inversion: homochiral helical nanotubes consisting of an achiral ligand.
The ligand tppda has been designed and synthesized as molecular leverage for helicity control when reacted with Cd(2+) ions. The guests MeOH or DMF preferentially stabilize the P-helical isomer, while the guest H2O causes a helix inversion to give the M-helical isomer as the major isomer without any chiral auxiliary.
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15 صفحه اولChiral Solvation Induced Supramolecular Chiral Assembly of Achiral Polymers
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ژورنال
عنوان ژورنال: Chemistry - A European Journal
سال: 2018
ISSN: 0947-6539
DOI: 10.1002/chem.201803227